Well-defined polyethylene molecular brushes by polyhomologation and ring opening metathesis polymerization

文献情報

出版日 2014-07-28

DOI 10.1039/C4PY00815D

インパクトファクター 5.582

著者

Yves Gnanou

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要旨

A novel strategy using polyhomologation and ring opening metathesis polymerization (ROMP) has been developed for the synthesis of well-defined polyethylene (PE) molecular brushes. Polyhomologation was used to afford an OH-terminated PE, which after transformation to the norbornyl PE macromonomer was subjected to ROMP. Kinetics of ROMP of the PE macromonomer was studied by in situ1H NMR monitoring. The brush structure was proved from HT-GPC, 1H NMR and DSC results.

掲載誌

Polymer Chemistry

CiteScore: 8.6

自己引用率: 7.3%

年間論文数: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

Well-defined polyethylene molecular brushes by polyhomologation and ring opening metathesis polymerization

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