Synthesis of multi-block copolymer stars using a simple iterative Cu(0)-mediated radical polymerization technique

文献情報

出版日 2011-09-30

DOI 10.1039/C1PY00384D

インパクトファクター 5.582

著者

Cyrille Boyer, Aurelia Derveaux, Per B. Zetterlund, Michael R. Whittaker

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要旨

In this communication, we describe a simple and highly efficient route to well-defined multi-block star copolymers based on copper(0)-mediated living radical polymerization. The technique involves a core first approach using a multi-functional initiator in connection with iterative copper(0)-mediated radical polymerization steps. Importantly, purification is not required between the successive chain extension steps as complete monomer conversion is reached before the addition of each consecutive monomer type.

掲載誌

Polymer Chemistry

CiteScore: 8.6

自己引用率: 7.3%

年間論文数: 457

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Synthesis of multi-block copolymer stars using a simple iterative Cu(0)-mediated radical polymerization technique

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