In situ back-side illumination fluorescence XAFS (BI-FXAFS) studies on platinum nanoparticles deposited on a HOPG surface as a model fuel cell: a new approach to the Pt-HOPG electrode/electrolyte interface
文献情報
Hiromitsu Uehara, Yohei Uemura, Takafumi Ogawa, Kentaro Kono, Ryoichi Ueno, Yasuhiro Niwa, Hiroaki Nitani, Hitoshi Abe, Satoru Takakusagi, Masaharu Nomura, Yasuhiro Iwasawa, Kiyotaka Asakura
We measured the in situ polarization-dependent X-ray absorption fine structure of platinum nanoparticles (PtNPs) deposited on a flat highly oriented pyrolytic graphite (HOPG) substrate under electrochemical conditions using a back-side illumination method. In this method, the thin HOPG substrate with PtNPs deposited on one side was used as a window for incident and fluorescent X-rays, as well as an electrode. A bent crystal Laue analyzer (BCLA) was applied to the extraction of the Pt Lα fluorescent X-ray signals from strong scattered X-rays. Pt L3 edge XAFS spectra were observed for various electrode potentials and polarization directions.
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Physical Chemistry Chemical Physics

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