RAFT copolymerization of alginate-derived macromonomers – synthesis of a well-defined poly(HEMAm)-graft-(1→4)-α-l-guluronan copolymer capable of ionotropic gelation

文献情報

出版日 2013-07-01

DOI 10.1039/C3PY00730H

インパクトファクター 5.582

著者

Ali Ghadban, Eric Reynaud, Marguerite Rinaudo, Luca Albertin

原文を見る

要旨

The aqueous RAFT copolymerization of methacrylamide- and methacrylate-functionalized (1→4)-α-L-guluronan and (1→4)-β-D-mannuronan macromonomers with N-(2-hydroxyethyl)methacrylamide afforded synthetic-g-polysaccharide copolymers with a predetermined and well-defined molar mass (“grafting through” approach). One such polymer featuring guluronan graft chains of Xn = 21 was able to undergo ionotropic gelation in the presence of Ca2+ ions and to form a soft hydrogel in spite of the fairly low molar mass (Mn = 77 000 Da). The high yield synthesis of a new methacrylate-functionalized (1→4)-α-L-guluronan is also reported.

掲載誌

Polymer Chemistry

CiteScore: 8.6

自己引用率: 7.3%

年間論文数: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

RAFT copolymerization of alginate-derived macromonomers – synthesis of a well-defined poly(HEMAm)-graft-(1→4)-α-l-guluronan copolymer capable of ionotropic gelation

文献情報

おすすめジャーナル

関連文献

Statistical thermodynamics unveils the dissolution mechanism of cellobiose

Metallic borophene polytypes as lightweight anode materials for non-lithium-ion batteries

Using molecular vibrations to probe exciton delocalization in films of perylene diimides with ultrafast mid-IR spectroscopy

Water and CO (co-)adsorption on pseudomorphic Pt films on Ru(0001) – a low-temperature scanning tunneling microscopy study

Exciton transport in π-conjugated polymers with conjugation defects

A bio-inspired strategy for the interfacial assembly of graphene oxide with in situ generated Ag/AgCl: designing sustainable hybrid photocatalysts

From force curves to surface nanomechanical properties

Dynamics of ethyl cellulose nanoparticle self-assembly at the interface of a nematic liquid crystal droplet

Effects of electrical conductivity on the formation and annihilation of positronium in porous materials

Correction: Elucidation of transport mechanism and enhanced alkali ion transference numbers in mixed alkali metal–organic ionic molten salts

こちらもおすすめ

3-(2-オキサプロピル)ベンzoic酸はどのように合成されますか？

BOC-L-3-氟苯丙氨酸の主な用途は何ですか？

4-メチル-4-ピペリジニル-1-ピロリドイン甲酸の主な用途は何ですか？

Biotin-PEG3-oxyamine HCl塩について、適切な化合物名称に適用される法規ガイドラインは何ですか？

N-(4-イソチオシアネートフェニル)-2-メトキシアリニンはどのように合成されますか？

金粉蕨亭2'-O-葡萄糖甙の主な用途は何ですか？

2-(2-ニトロフェニル)酢酸ヒドライドの物理化学的性質は何ですか？

5-(ヒドロキシメチル)-2-チオキソ-2,3-ジヒドロピリミジン-4(1H)-オンを取り扱う際の実験室安全事項は何ですか？

11-脱氢血栓烷 b2の市場動向や研究トレンドはどうですか？

3,3-二甲基哌啶-4-酮はどのように保存すればよいですか？

掲載誌

Polymer Chemistry

おすすめ化合物

3-(3-Methoxybenzyl)pyrrolidine-2,5-dione

1-(3,4-Diethoxyphenyl)ethanone

1-ethyl-1H-pyrazole-5-carbaldehyde

(2E)-4-[(1R,2S,8R,19S,21R)-14-Hydroxy-11-isopropenyl-8,23,23-trimethyl-5-(3-methyl-2-buten-1-yl)-16,20-dioxo-3,7,22-trioxaheptacyclo[17.4.1.1~8,12~.0~2,17~.0~2,21~.0~4,15~.0~6,13~]pentacosa-4(15),5,13 ,17-tetraen-21-yl]-2-methyl-2-butenoic acid

2-Isopropoxybenzaldehyde

おすすめサプライヤー