Photoinduced polyaddition of multifunctional azides and alkynes

文献情報

出版日 2013-04-24

DOI 10.1039/C3PY00356F

インパクトファクター 5.582

著者

Peter Burtscher, Norbert Moszner

原文を見る

要旨

The photoinduced copper(I)-catalyzed polymerization of multifunctional azides and alkynes is facilitated by the photoreduction of copper(II) acetate generating copper(I) ions without using any additional photoinitiator. The polymerization can only be carried out in solution using at least 15 wt% of methanol. Depending on the catalyst concentration quantitative monomer conversions can be achieved allowing the determination of the mechanical properties. The bifunctional system consisting of a di-azide and di-alkyne exhibited the highest Young's modulus value of 1600 MPa.

掲載誌

Polymer Chemistry

CiteScore: 8.6

自己引用率: 7.3%

年間論文数: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

Photoinduced polyaddition of multifunctional azides and alkynes

文献情報

おすすめジャーナル

関連文献

Effect of composition and coating on the interparticle interactions and magnetic hardness of MFe2O4 (M = Fe, Co, Zn) nanoparticles

Defects in crystalline PVDF: a density functional theory-density functional tight binding study

Chiral segregation driven by a dynamical response of the adsorption footprint to the local adsorption environment: bitartrate on Cu(110)

Transdermal cellular membrane penetration of proteins with gold nanoparticles: a molecular dynamics study

Magnetic trapping of SH radicals

Metallic borophene polytypes as lightweight anode materials for non-lithium-ion batteries

Theoretical study of the substituent effect controlling the radiative and non-radiative decay processes of platinum(ii) complexes

Non-covalent interactions in anisole–(CO2)n (n = 1, 2) complexes

Probing RbBr solvation in freestanding sub-2 nm water clusters

Amphiphilic nanosheet self-assembly at the water/oil interface: computer simulations

こちらもおすすめ

3-(2-オキサプロピル)ベンzoic酸はどのように合成されますか？

BOC-L-3-氟苯丙氨酸の主な用途は何ですか？

4-メチル-4-ピペリジニル-1-ピロリドイン甲酸の主な用途は何ですか？

Biotin-PEG3-oxyamine HCl塩について、適切な化合物名称に適用される法規ガイドラインは何ですか？

N-(4-イソチオシアネートフェニル)-2-メトキシアリニンはどのように合成されますか？

金粉蕨亭2'-O-葡萄糖甙の主な用途は何ですか？

2-(2-ニトロフェニル)酢酸ヒドライドの物理化学的性質は何ですか？

5-(ヒドロキシメチル)-2-チオキソ-2,3-ジヒドロピリミジン-4(1H)-オンを取り扱う際の実験室安全事項は何ですか？

11-脱氢血栓烷 b2の市場動向や研究トレンドはどうですか？

3,3-二甲基哌啶-4-酮はどのように保存すればよいですか？

掲載誌

Polymer Chemistry

おすすめ化合物

(2E)-4-[(1R,2S,8R,19S,21R)-14-Hydroxy-11-isopropenyl-8,23,23-trimethyl-5-(3-methyl-2-buten-1-yl)-16,20-dioxo-3,7,22-trioxaheptacyclo[17.4.1.1~8,12~.0~2,17~.0~2,21~.0~4,15~.0~6,13~]pentacosa-4(15),5,13 ,17-tetraen-21-yl]-2-methyl-2-butenoic acid

4-Cyclohexene-1,2-dicarboxylic acid, 1,2-dimethyl ester, (1R,2R)-rel-

3-Bromo-2-chloro-4-iodopyridine

[4-Chloro-3-(diethylcarbamoyl)phenyl]boronic acid

Ethyl 6-(trifluoromethyl)pyridazine-3-carboxylate

おすすめサプライヤー