Isolation and structural characterization of an optically active intermediate in the oxidative addition of methyl iodide on a rhodium(i) centre

文献情報

出版日 2004-08-25

DOI 10.1039/B409134E

インパクトファクター 6.222

著者

Angelino Doppiu, Ulli Englert, Albrecht Salzer

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要旨

The optically pure cationic complex (S,SRh)-[Rh(η5-C5H4CH2CH(Ph)PPh2-κP)(η2-CH2CH2)(CH3)][I] is the first example of a key intermediate in the oxidative addition reaction of methyl iodide on a rhodium(I) centre which has been structurally characterized by X-ray diffraction.

掲載誌

Chemical Communications

CiteScore: 8.6

自己引用率: 4.7%

年間論文数: 2458

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Isolation and structural characterization of an optically active intermediate in the oxidative addition of methyl iodide on a rhodium(i) centre

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