Productive sugar isomerization with highly active Sn in dealuminated β zeolites
文献情報
Jan Dijkmans, Dries Gabriëls, Michiel Dusselier, Filip de Clippel, Pieter Vanelderen, Kristof Houthoofd, Annelies Malfliet, Yiannis Pontikes, Bert F. Sels
A water-tolerant Lewis acid catalyst was synthesized by grafting SnIV in isopropanol under reflux onto dealuminated zeolites with the BEA (β) topology. This synthesis method allows the production of highly active Snβ-type catalysts without the need for long hydrothermal syntheses or hydrogen fluoride, while using cheap Sn-precursors, industrially available β zeolites and standard catalyst synthesis unit operations. Extensive characterization of the best catalyst shows highly dispersed Sn in the zeolite matrix (XRD, 29Si MAS NMR and 1H MAS NMR) without the formation of SnO2 (XRD and UV-Vis). The catalyst was tested for the model isomerization of sugars such as glucose to fructose. The catalytic activity proved to be purely heterogeneous and the catalyst was recycled and reused without significant loss in activity. Isomerization productivities above 4 kg product per kg of catalyst per hour are reported with appreciably low Sn loadings, corresponding to exceptionally high turnover frequencies, viz. 500 cycles per Sn per hour at 110 °C, which surpass the activity per Sn of the original hydrothermally synthesized Snβ.
おすすめジャーナル

Electroanalysis

Medicinal Chemistry Research

Bioorganic & Medicinal Chemistry

Acta Metallurgica Sinica-English Letters

Atomization and Sprays

Bioorganic & Medicinal Chemistry Letters

Critical Reviews in Solid State and Materials Sciences

Journal of Asian Natural Products Research

Topics in Catalysis

Polycyclic Aromatic Compounds
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