Selective oxidation of dimethyl ether to methyl formate over trifunctional MoO3–SnO2catalyst under mild conditions
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Qingde Zhang, Yizhuo Han, Yisheng Tan
Dimethyl ether oxidation was conducted over MoO3–SnO2 catalysts prepared from different Sn salt precursors. Over the MoO3–SnO2 catalyst prepared from SnCl4, methyl formate selectivity reached 94.1% at 433 K without the formation of COx. The performance of the catalyst was determined by the existence form of MoO3 and the different surface bonding of Mo and O of the catalyst.
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