C60fullerene aggregation in aqueous solution
文献情報
Yuriy I. Prylutskyy, Anatoly S. Buchelnikov, Dmitry P. Voronin, Viktor V. Kostjukov, Uwe Ritter, John A. Parkinson, Maxim P. Evstigneev
In the present work we develop a novel approach for quantification of the energetics of C60 fullerene aggregation in aqueous media in terms of equilibrium aggregation constant KF. In particular, it is shown that the experimental determination of the magnitude of KF is possible only within the framework of the ‘up-scaled aggregation model’, considering the C60 fullerene water solution as a solution of fullerene clusters. Using dynamic light scattering (DLS) data we report the value, KF = 56 000 M−1, which is in good agreement with existing theoretical estimates and the results of energetic analyses. It is suggested that the proposed ‘up-scaled model’ may be used in any instances of non-specific aggregation resulting in formation of large spherical particles. The measurement of the translational diffusion coefficient and the dimensions of the light scattering particles using a DLS approach with respect to C60 fullerene aggregates is found to contain significant systematic errors originating from the interaction effect that is well-known for micellar solutions. As a result, corrections to the equations associated with DLS data are proposed.
おすすめジャーナル

Journal of Physics and Chemistry of Solids

Helvetica Chimica Acta

European Journal of Wood and Wood Products

Kinetics and Catalysis

Pharmacological Reviews

Journal of Catalysis

Journal of Heterocyclic Chemistry

Journal of Organometallic Chemistry

Organic Preparations and Procedures International

Fibre Chemistry
関連文献
Protein hydration in living cells probed by Fourier transform infrared (FT-IR) spectroscopic imaging
B. Turner, J. Mizukado, S. G. Kazarian
DOI: 10.1039/C7AN00337D
Electrochemical sensing of hepatocyte viability
Shang-heng Tsai, Wei-Jen Ting, Chao-Chin Hu, C. Bor Fuh
DOI: 10.1039/C3AN02226A
Ratiometric fluorescent probes based on through-bond energy transfer of cyanine donors to near-infrared hemicyanine acceptors for mitochondrial pH detection and monitoring of mitophagy
Shuai Xia, Yibin Zhang, Nick Whisman, Jianheng Bi, Tessa E. Steenwinkel, Shulin Wan, Jerry Medford, Momoko Tajiri, Rudy L. Luck, Thomas Werner, Haiying Liu
DOI: 10.1039/C9TB02302J
CuO promoted Mn2O3-based materials for solid fuel combustion with inherent CO2 capture
D. Hosseini, Q. Imtiaz, P. M. Abdala, S. Yoon, A. M. Kierzkowska, A. Weidenkaff, C. R. Müller
DOI: 10.1039/C5TA01088H
Label-free and highly sensitive detection of DNA adenine methylation methyltransferase through cathodic photoelectrochemistry
Fang Li, Xiuming Wu, Mengmeng Gu, Guang-Li Wang
DOI: 10.1039/D0AN02438D
An “off–on–off” fluorescence chemosensor for the sensitive detection of Cu2+ in aqueous solution based on multiple fluorescence emission mechanisms
Aimei Zhou, Shuhua Han
DOI: 10.1039/D0AN02472D
Development of a PCR-free electrochemical point of care test for clinical detection of methicillin resistant Staphylococcus aureus (MRSA)
H. Schulze, G. Henihan, A. Hardie, I. Ciani, G. Giraud, J. G. Terry, A. J. Walton, R. Pethig, P. Ghazal, K. E. Templeton, A. R. Mount, T. T. Bachmann
DOI: 10.1039/C3AN01319G
Correction: Redox-responsive, reversibly fluorescent nanoparticles from sustainable cellulose derivatives
Wei Wang, Wei Li, Kai Zhang
DOI: 10.1039/C5TA90092A
こちらもおすすめ
3-イチチルビフェニルはどのように合成されますか?
3-イチチルビフェニルは、ビフェニルとイチプロピオニトリルを回収率約90%で反応させて合成されます。触媒は通常、亜リチウムホウ素を用います。
8-溴-5-三氟甲基喹啉はどのように合成されますか?
8-溴-5-三氟甲基喹啉は、5-トリフルオロメチル-2-メチル-1,3-ベンゼンジオールをブロモエタノールと反応させて生成します。この反応は塩基性条件下で行われ...
ジメチル4-(4,4,5,5-テトラメチル-1,3,2-ドioxaborolan-2-基)-2,6-ピリジンジカルボイル酸フェニルアミニドの代替品はありますか?
ジメチル4-(4,4,5,5-テトラメチル-1,3,2-ドioxaborolan-2-基)-2,6-ピリジンジカルボイル酸フェニルアミニドの代替品としては、4-...
N-(3,5-ヘキサクロロ-4-ピリドインイル)-8-メチオキシ-5-キノリンカーボン酸の市場動向や研究トレンドはどのようなものでしょうか?
N-(3,5-ヘキサクロロ-4-ピリドインイル)-8-メチオキシ-5-キノリンカーボン酸の市場動向は、主に産業用途での需要により影響を受けます。研究トレンドとし...
イソステアロイルグリセリルは安全ですか?
イソステアロイルグリセリルは一般的に安全性が高いとされていますが、過度な使用や個人差により皮�owsん炎などの反応が起こる可能性があります。使用前に医師に相談す...
1-(二苯甲基)-3,3-二氟-氮杂环丁烷の市場動向や研究トレンドはどうですか?
1-(二苯甲基)-3,3-二氟-氮杂环丁烷の市場動向は、医薬品や合成化学の研究分野で注目を集めています。新興研究は、該当化合物の合成改良と生体内での作用メカニズ...
3-チオフェンスチオールの物理化学的性質は何ですか?
3-チオフェンスチオールのCAS番号は7774-73-4です。結晶性の白色粉末で、分子量は122.17です。この化合物は水に微溶解し、エタノールやジクロロメタン...
2-Methyl-2-propanyl (2S)-2-(aminomethyl)-1-piperidinecarboxylateは安全ですか?
2-Methyl-2-propanyl (2S)-2-(aminomethyl)-1-piperidinecarboxylateは一定の安全性基準を満たしていま...
CAS番号1316822-90-8の化合物は安全ですか?
CAS番号1316822-90-8の化合物は安全性に関しては評価が不足していますが、一般的には生物学的に活性な物質であり、取り扱いには適切な安全防護措置が必要で...
Tert-butyl 2-(2-羟基乙基)哌嗪-1-羧酸はどのように保存すればよいですか?
Tert-butyl 2-(2-羟基乙基)哌嗪-1-羧酸は、冷暗所で保存し、直射日光から遠ざけてください。容器は密閉し、高湿度や高温を避けて保管してください。
掲載誌
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.


![1-oxaspiro[4.4]nonan-6-one structure 1-oxaspiro[4.4]nonan-6-one structure](https://static.chemtradehub.com/structs/134/134179-01-4-e051.webp)

