A click chemistry approach to the efficient synthesis of polyoxometalate–polymer hybrids with well-defined structures

文献情報

出版日 2012-01-18

DOI 10.1039/C2PY00546H

インパクトファクター 5.582

著者

Min-Biao Hu, Nan Xia, Wei Yu, Chi Ma, Jing Tang, Zhan-Yao Hou, Ping Zheng, Wei Wang

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要旨

In this study a click chemistry approach was used to synthesize polyoxometalate–polymer hybrids with well-defined structures. The starting materials were a two-azido-containing organosilyl derivative of a Wells-Dawson-type polyoxometalate and a propargyl-terminated poly(ε-caprolactone). The clicking reaction between the azido groups and alkynyl groups was found to be very efficient and the structures of the hybrids were well-defined. This breakthrough will promote a great development in the synthesis of various polyoxometalate–polymer hybrids and broaden their potential application.

掲載誌

Polymer Chemistry

CiteScore: 8.6

自己引用率: 7.3%

年間論文数: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

A click chemistry approach to the efficient synthesis of polyoxometalate–polymer hybrids with well-defined structures

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