Hierarchical TiO2 flowers built from TiO2nanotubes for efficient Pt-free based flexible dye-sensitized solar cells
文献情報
Bing-Xin Lei, Qiu-Ping Luo, Xiao-Yun Yu, Wu-Qiang Wu, Cheng-Yong Su, Dai-Bin Kuang
A novel hierarchical TiO2 flower consisting of anatase TiO2 nanotubes on a Ti foil substrate has been prepared via a mild hydrothermal reaction of TiO2 nanoparticles/Ti foil. The photovoltaic performance of DSSC based on hierarchical TiO2 flowers/Ti (7.2%) is much higher than that of TiO2 nanoparticle/Ti (6.63%) because of its superior light scattering ability and fast electron transport. Moreover, full flexible DSSC based on the novel hierarchical TiO2 flowers/Ti foil photoelectrode and electrodeposited poly(3,4-ethylenedioxythiophene) (PEDOT) on indium tin oxide-coated poly(ethylene terephthalate) (ITO-PET) counter electrode shows a significant power conversion efficiency of 6.26%, accompanying a short-circuit current density of 11.96 mA cm−2, an open-circuit voltage of 761 mV and a fill factor of 0.69.
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Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.













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