Antioxidant-substituted tetrapyrazinoporphyrazine as a fluorescent sensor for basic anions‡§
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Navaneetha K. Subbaiyan, Francis D’Souza, Yongshu Xie, Satyajit Sahu, Noelia M. Sanchez-Ballester, Toshiyuki Mori
Tetrapyrazinoporphyrazine substituted at its periphery with eight antioxidant 3,5-di-t-butyl-4-hydroxyphenyl groups behaves as a turn-on fluorescent sensor for fluoride anions. Conversely, the precursor antioxidant-substituted 1,2-phthalonitrile was found to act in turn-off mode suggesting that the origin of the phenomenon lies at the phenolate-substituted 1,4-pyrazinyl moiety.
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