Macromolecular design of poly(vinyl alcohol) by RAFT polymerization

文献情報

出版日 2011-10-19

DOI 10.1039/C1PY00429H

インパクトファクター 5.582

著者

Anton A. A. Smith, Thomas Hussmann, Joseph Elich, Almar Postma, Marie-Helene Alves, Alexander N. Zelikin

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要旨

Reversible Addition–Fragmentation chain Transfer polymerization (RAFT) is employed herein to obtain the first example of poly(vinyl alcohol), PVA, with controlled molecular weight and terminal aminegroups thus presenting a flexible tool for materials design and bioconjugation. Furthermore, we demonstrate that RAFT control can be used to facilitate syndiotactic chain propagation and obtain PVA with the highest reported content of syndiotactic dyad (∼78%).

掲載誌

Polymer Chemistry

CiteScore: 8.6

自己引用率: 7.3%

年間論文数: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

Macromolecular design of poly(vinyl alcohol) by RAFT polymerization

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