Polymerization of 4-vinylpyridine and N,N-dimethylacrylamide using a system without organic initiator

文献情報

出版日 2011-07-27

DOI 10.1039/C1PY00223F

インパクトファクター 5.582

著者

Sijing Xia, Bin Yang, Guangzhao Li, Xiaoqing Zhu, Anning Wang, Jin Zhu

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要旨

Polymerization of monomer 4-vinylpyridine (4VP) and N,N-dimethylacrylamide (DMAA) could be carried out using a system without organic initiator. It was found that metal catalyst (CuCl) and water played a vital role in this process through a series of control experiments. Polymers with high degrees of polymerization (Mp = 128739 for P4VP and Mp = 355122 for PDMAA) have been obtained by the addition of Au nanoparticles (AuNPs). Radical inhibitor and electron spin resonance (ESR) spin-trapping techniques have been used to analyze the polymerization process and identify the involvement of radicals in the reaction.

掲載誌

Polymer Chemistry

CiteScore: 8.6

自己引用率: 7.3%

年間論文数: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

Polymerization of 4-vinylpyridine and N,N-dimethylacrylamide using a system without organic initiator

文献情報

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Polymer Chemistry

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