Synthesis of catalytically active porous organic polymers from metalloporphyrin building blocks

文献情報

出版日 2011-01-04

DOI 10.1039/C0SC00339E

インパクトファクター 9.825

著者

Abraham M. Shultz, Omar K. Farha, Joseph T. Hupp, SonBinh T. Nguyen

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要旨

The synthesis of a porous organic polymer (POP) containing free-base porphyrin subunits has been accomplished by the condensation of a bis(phthalic acid)porphyrin with tetra(4-aminophenyl)methane. Metallation by post-synthesis modification affords microporous materials incorporating either Fe or Mn(porphyrins) that have been shown to be active catalysts for both olefin epoxidation and alkane hydroxylation.

掲載誌

Chemical Science

CiteScore: 14.4

自己引用率: 3.9%

年間論文数: 1413

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Synthesis of catalytically active porous organic polymers from metalloporphyrin building blocks

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