Effect of monomer/oxidant mole ratio on polymerization mechanism, conductivity and spectral characteristics of mechanochemically prepared polypyrrole

文献情報

出版日 2010-09-30

DOI 10.1039/C0PY00212G

インパクトファクター 5.582

著者

Oleg Yu. Posudievsky, Olga A. Kozarenko

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要旨

The effect of the composition of the initial reaction mixture – pyrrole/oxidant mole ratio – on the mechanism of mechanochemical polymerization of pyrrole was studied. Experimental evidence in favor of the chain mechanism for mechanochemical formation of the highly conducting PPy at high monomer/oxidant mole ratio was first obtained. Interrelation between polymerization mechanism and structure, conductivity and spectral characteristics of the prepared polypyrrole samples was considered.

掲載誌

Polymer Chemistry

CiteScore: 8.6

自己引用率: 7.3%

年間論文数: 457

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Effect of monomer/oxidant mole ratio on polymerization mechanism, conductivity and spectral characteristics of mechanochemically prepared polypyrrole

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