Facile synthesis of a conjugated microporous polymeric monolith via copper-free Sonogashira–Hagihara cross-coupling in water under aerobic conditions‡

文献情報

出版日 2015-06-02

DOI 10.1039/C5PY00772K

インパクトファクター 5.582

著者

Jie Liu, John M. Tobin, Zhengtao Xu, Filipe Vilela

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要旨

A conjugated microporous polymer was synthesized via a modified Sonogashira–Hagihara cross-coupling reaction under aerobic conditions in water and in the absence of copper. These conditions allowed the directing of the CMP format during synthesis into a monolithic structure. Post-modification of the polymer with thiol–yne chemistry followed by AgI uptake led to a catalytically active material for a heterocyclization reaction.

掲載誌

Polymer Chemistry

CiteScore: 8.6

自己引用率: 7.3%

年間論文数: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

Facile synthesis of a conjugated microporous polymeric monolith via copper-free Sonogashira–Hagihara cross-coupling in water under aerobic conditions‡

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