Facile and selective synthesis of aldehyde end-functionalized polymers using a combination of catalytic chain transfer and rhodium catalyzed hydroformylation

文献情報

出版日 2010-05-28

DOI 10.1039/C0PY00111B

インパクトファクター 5.582

著者

Niels M. B. Smeets, Jan Meuldijk, Johan P. A. Heuts, Ard C. J. Koeken

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要旨

A novel synthetic pathway towards aldehyde end-functionalized polymers is presented from a combination of catalytic chain transfer polymerization (CCTP) and rhodium catalyzed hydroformylation in supercritical carbon dioxide. CCTP allows for the synthesis of well-defined macromonomers in terms of the average molecular weight and the terminal unit carrying the unsaturated bond. The rhodium catalyzed hydroformylation allows for a high selectivity towards aldehyde end-group functionalized polymers. The introduction of the synthetically versatile aldehyde end-group opens up a broad range of possible applications.

掲載誌

Polymer Chemistry

CiteScore: 8.6

自己引用率: 7.3%

年間論文数: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

Facile and selective synthesis of aldehyde end-functionalized polymers using a combination of catalytic chain transfer and rhodium catalyzed hydroformylation

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