New organic–inorganic hybrid microporous organosilica having high metal ion adsorption capacity
文献情報
Manidipa Paul, Nabanita Pal, P. R. Rajamohanan, Bharat S. Rana, Anil K. Sinha, Asim Bhaumik
A new microporous organic–inorganic hybrid organosilica LHMM-2 containing a bis(propyliminomethyl)benzene moiety inside the framework has been synthesized hydrothermally without using any template or structure-directing agent. Powder XRD and TEM image analyses suggest a new disordered microporous structure with pores of dimension ca. 0.54 nm, and 13C and 29Si MAS NMR and spectroscopic results indicate the presence of bridging organic bis(propyliminomethyl)benzene moiety in this framework. TPD-NH3 results suggested that nearly 5 times as much bis(propyliminomethyl)benzene moiety is located inside the micropore walls (matrix) than in the surface of the pores. LHMM-2 shows very high adsorption capacity for metal cations like Fe3+, Cu2+ and Zn2+.
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Colloid Journal

Herald of the Russian Academy of Sciences

Acta Metallurgica Sinica-English Letters

Medicinal Chemistry Research

Bioorganic & Medicinal Chemistry Letters

Chinese Journal of Chemistry

Main Group Chemistry

Journal of Chemical Sciences

Atomization and Sprays

Critical Reviews in Solid State and Materials Sciences
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