Nanoenergetic materials: boron nanoparticles from the pyrolysis of decaborane and their functionalisation
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Brian J. Bellott, Wontae Noh, Ralph G. Nuzzo, Gregory S. Girolami
The surfaces of boron nanoparticles 10–150 nm in diameter, prepared by gas phase pyrolysis of decaborane vapour at 1 atm and 700–900 °C, can be halogenated by treatment with Br2 or XeF2; the surface halogenation somewhat increases the onset temperature for the oxidation of the particles under O2.
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