Cyanide-bridged tetradecanuclear RuII3MII11clusters (MII = ZnII and CuII) based on the high connectivity building block [Ru3(HAT)(CN)12]6−: structural and photophysical properties‡

文献情報

出版日 2008-07-25

DOI 10.1039/B807364C

インパクトファクター 6.222

著者

Juan Manuel Herrera, Enrique Colacio, Corine Mathonière, Duane Choquesillo-Lazarte, Michael D. Ward

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要旨

Reaction of the anionic cyanometallate chromophore [{Ru(CN)4}3(μ3-HAT)]6− with [MII(tren)]2+ complexes (M = ZnII, CuII) provides discrete tetradecanuclear clusters of formula [{MII(tren)(μ-CN)}11{Ru3(HAT)(CN)}]16+; the weak luminescence of the Ru3 chromophore is substantially enhanced in the presence of ZnII ions, whereas it is completely quenched when CuII centers are present.

掲載誌

Chemical Communications

CiteScore: 8.6

自己引用率: 4.7%

年間論文数: 2458

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

Cyanide-bridged tetradecanuclear RuII3MII11clusters (MII = ZnII and CuII) based on the high connectivity building block [Ru3(HAT)(CN)12]6−: structural and photophysical properties‡

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