Challenging the absence of observable hydrogens in the assignment of absolute configurations by NMR: application to chiral primary alcohols

文献情報

出版日 2007-01-30

DOI 10.1039/B617184B

インパクトファクター 6.222

著者

Félix Freire, José Manuel Seco, Emilio Quiñoá, Ricardo Riguera

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要旨

The absolute configuration of β-chiral primary alcohols devoid of observable hydrogens on one of the β-substituents at the asymmetric carbon (L1/L2) can be determined by comparison of the 1H NMR of their (R)- and (S)-9-AMA ester derivatives and analysis of the ΔδRS for the L substituent and the Cβ-H.

掲載誌

Chemical Communications

CiteScore: 8.6

自己引用率: 4.7%

年間論文数: 2458

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