Rotationally resolved electronic spectroscopy of tryptophol in the gas phase

文献情報

出版日 2005-09-12

DOI 10.1039/B508610H

インパクトファクター 3.676

著者

John T. Yi, David W. Pratt

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要旨

High resolution S1–S0 fluorescence excitation spectra of tryptophol have been observed in the collision-free environment of a supersonic beam. Each origin band has been assigned to a unique conformer based on its observed rotational constants. Unlike its close relative tryptamine, which exhibits seven distinguishable conformers under similar conditions, tryptophol exhibits only four (GPy-in, GPh-in, and two anti structures). Possible reasons for this difference in behavior are discussed.

掲載誌

Physical Chemistry Chemical Physics

CiteScore: 5.5

自己引用率: 10.3%

年間論文数: 3036

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