Reversible caterpillar-motion like isomerization in a N,N′-dimethyl hexaphyrin(1.1.1.1.1.1) induced by two-electron oxidation or reduction

文献情報

出版日 2005-06-23

DOI 10.1039/B506586K

インパクトファクター 6.222

著者

Masaaki Suzuki, Atsuhiro Osuka

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要旨

Caterpillar-motion like rotational isomerization of meso-aryl substituted [26]- and [28]hexaphyrins has been revealed for the first time. Two-electron oxidation and reduction induce reversible interconversion between N,N′-dimethyl [26]- and [28]hexaphyrins with a rotational isomerization, in which the N-methylated pyrroles move from the corner in the former to the centre in the latter.

掲載誌

Chemical Communications

CiteScore: 8.6

自己引用率: 4.7%

年間論文数: 2458

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

Reversible caterpillar-motion like isomerization in a N,N′-dimethyl hexaphyrin(1.1.1.1.1.1) induced by two-electron oxidation or reduction

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