Mechanism of hydrogen transfer to imines from a hydroxycyclopentadienyl ruthenium hydride. Support for a stepwise mechanism

文献情報

出版日 2004-10-06

DOI 10.1039/B410698A

インパクトファクター 6.222

著者

Joseph S. M. Samec, Alida H. Éll, Jan-E. Bäckvall

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要旨

The negligible double kinetic deuterium isotope effect (kHH/kDD = 1.05) in the reaction where [2,3,4,5-Ph4(η5-C4COH)Ru(CO)2H (2) transfers a hydride and a proton to N-phenyl-[1-(4-methoxyphenyl)ethylidene]amine (4) indicates that no bond to hydrogen is broken or formed in the rate-determining step.

掲載誌

Chemical Communications

CiteScore: 8.6

自己引用率: 4.7%

年間論文数: 2458

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