An automatic method for the determination of carcinogenic 1-nitropyrene in extracts from automobile exhaust particulate matter

文献情報

出版日 2003-10-16

DOI 10.1039/B308207E

インパクトファクター 4.616

著者

Fumiko Tsuruga, Sousuke Sasaki

原文を見る

要旨

An automatic method for the determination of carcinogenic 1-nitropyrene in extracts from automobile exhaust particulate matter has been developed. Organic matter was extracted from particulate matter and the extract was concentrated. Then the extract was injected into a two-dimensional (2D) high-performance liquid chromatograph (HPLC) with a fluorescence detection system. To improve the sensitivity a large sample volume (300 µl) was applied to the HPLC system using the double on-column focusing technique. To achieve full automation and high selectivity a reduction column packed with platinum black was introduced after the 2D HPLC system using a C18 column as the primary column and a pentabromobenzyl column as the secondary column. This HPLC system could determine 0.01–3,000 ng ml−1 of 1-nitropyrene in an extract from diesel and gasoline exhaust particulate matter at 40 min intervals.

掲載誌

Analyst

CiteScore: 7.8

自己引用率: 5.6%

年間論文数: 653

Analyst publishes analytical and bioanalytical research that reports premier fundamental discoveries and inventions, and the applications of those discoveries, unconfined by traditional discipline barriers.

An automatic method for the determination of carcinogenic 1-nitropyrene in extracts from automobile exhaust particulate matter

文献情報

おすすめジャーナル

関連文献

Thiol–yne click chemistry on carbon nanotubes for mediated bioelectrocatalytic glucose oxidation

Electrochemically exfoliated covalent organic frameworks for improved photocatalytic hydrogen evolution

Fe-based dual-atom catalysts for the oxygen reduction reaction

Unveiling the magnetic ordering effect in La-doped Ti3C2O2 MXenes on electrocatalytic CO2 reduction

Contents list

Expanding the horizons of covalent organic frameworks: sub-stoichiometric synthesis as an emerging toolkit for functional COFs

Front cover

Spiro[fluorene-9,9′-xanthene]-based hole shuttle materials for effective defect passivation in perovskite solar cells

Fast redox conversion in lithium–sulfur batteries enabled by Cu-doped W18O49 with abundant oxygen defects

From wasted polymers to N/O co-doped partially graphitic carbon with hierarchical porous architecture as a promising cathode for high performance Zn-ion hybrid supercapacitors

こちらもおすすめ

噻奈普汀乙酯の物理化学的性質は何ですか？

アミピシリン不純物Fとは何ですか？

イリジウム(I)ヘキサフルオロフォスファートの代替品はありますか？

含有3-(苯氧基甲基)苯硼酸频那醇酯の廃棄物はどのように処理すべきですか？

2-甲基辛-1-醇を取り扱う際の実験室安全事項は何ですか？

高氯酸钪の代替品はありますか？

3α-アセトキノイドコレステロールエステルはどのように保存すればよいですか？

2-ぶンジロキシ-4-(トリフルオロメチル)フェノルビノン酸の主な用途は何ですか？

(2S,3R)-2-氨基-3-甲基丁二酸はどのように合成されますか？

1-Benzyl-2-phenyl-1H-imidazoleはどのように保存すればよいですか？

掲載誌

Analyst

おすすめ化合物

N-(4-Chlorophenyl)-3-oxobutanamide

Trt-Cys(Trt)-OH DEA

4-bromobenzenesulfinic Acid

4-(4-{4-[4-Fluoro-3-(trifluoromethyl)phenyl]-1-methyl-1H-imidazol-2-yl}-1-piperidinyl)-1H-pyrazolo[3,4-d]pyrimidine 4-methylbenzenesulfonate (1:1)

4-chloro-N-[5-methyl-2-(7H-pyrrolo[2,3-d]pyrimidine-4-carbonyl)-3-pyridyl]-3-(trifluoromethyl)benzenesulfonamide

おすすめサプライヤー