A novel copper organophosphonate with a pore-like 3D framework and Cu–Cu magnetic ordering

文献情報

出版日 2003-06-13

DOI 10.1039/B304610A

インパクトファクター 6.222

著者

Deyuan Kong, Yang Li, Joseph H. Ross Jr., Abraham Clearfield

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要旨

H2O3PCH2NH2+CH2PO3H− was hydrothermally reacted with Cu(II) in aqueous solution at a 1 : 1 ratio, forming Cu3[NH2(CH2PO3)2]2 (1). Two kinds of coordination environments exist around the central copper ions: a distorted square planar Cu(1) ion and an octahedral Cu(2) ion. They are bridged with one terminal oxygen atom forming a 3D-coordination framework of layers sharing corners. Novel antiferromagnetic coupling between the two kinds of Cu units was observed at 15 K, followed by ferromagnetic ordering at 9 K.

掲載誌

Chemical Communications

CiteScore: 8.6

自己引用率: 4.7%

年間論文数: 2458

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

A novel copper organophosphonate with a pore-like 3D framework and Cu–Cu magnetic ordering

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