FTIR spectroscopy of carbon dioxide adsorbed on sodium- and magnesium-exchanged ETS-10 molecular sieves
文献情報
F. X. Llabrés i Xamena, A. Zecchina
The adsorption of carbon dioxide on sodium- and magnesium-exchanged ETS-10 molecular sieves was investigated by FTIR spectroscopy. CO2 was found to adsorb reversibly onto the charge-balancing cations with formation of linear end-on adducts of the type M⋯OCO (with M = Na+ or Mg2+). Such adducts are characterised by intense ν3 bands at 2353 and 2365 cm−1, for CO2 interacting with Na+ and Mg2+, respectively. More interestingly, carbon dioxide was also found to form different carbonate-like species upon adsorption on the Na-ETS-10 (and, to a minor extent, also on Mg-ETS-10), which are the origin of the activity of ETS-10 in heterogeneous base-catalysed processes.
関連文献
Mechanical disassembly of human picobirnavirus like particles indicates that cargo retention is tuned by the RNA–coat protein interaction
Javier M. Rodríguez
DOI: 10.1039/D3NH00195D
Correction: Hydrothermal synthesis of α-MnO2 and β-MnO2 nanorods as high capacity cathode materials for sodium ion batteries
Dawei Su, Hyo-Jun Ahn
DOI: 10.1039/D3TA90111D
Two-gap topological superconductor LaB2 with high Tc = 30 K
Chin-Hsuan Chen, Ye-Shun Lan, Angus Huang
DOI: 10.1039/D3NH00249G
Improving the electrochemical performance of Li2S cathodes based on point defect control with cation/anion dual doping
Wenli Pan, Nobuya Machida, Toshiyuki Matsunaga, Mukesh Kumar, Neha Thakur, Toshiki Watanabe, Atsushi Sakuda, Akitoshi Hayashi, Masahiro Tatsumisago, Yoshiharu Uchimoto
DOI: 10.1039/D3TA05426H
Enriching 2D transition metal borides via MB XMenes (M = Fe, Co, Ir): Strong correlation and magnetism
Jiawei Tang, Duo Wang, Jing Zhang, Litao Sun, Baisheng Sa, Bobby G. Sumpter, Jingsong Huang, Weiwei Sun
DOI: 10.1039/D3NH00364G
Low-cost and high-performance selenium indoor photovoltaics
Zongbao Li, Mingjie Feng, Bin Yan
DOI: 10.1039/D3TA04530G
Crystal structure, infrared spectroscopy and thermodynamic properties of a manganese member of the ellenbergerite family
Larisa V. Shvanskaya, Polina V. Krikunova, Tatyana M. Vasilchikova, Elena Y. Borovikova, Olga S. Volkova, Alexander N. Vasiliev
DOI: 10.1039/D3NJ05142K
A single-phase gadolinium-doped ceria cathode for highly efficient CO2 electrolysis
Ahmad Shaur, Michel Drazkowski, Shaochen Zhu, Bernard Boukamp
DOI: 10.1039/D3TA03977C
A selenoureido-iminoglycolipid transported by zeolitic-imidazolate framework nanoparticles: a novel antioxidant therapeutic approach
Fátima Guerrero, Andrés Carmona, Victoria Vidal, Ana Franco, Alejandro Martín-Malo, Elena M. Sánchez-Fernández, Carolina Carrillo-Carrión
DOI: 10.1039/D3NH00363A
こちらもおすすめ
アエポキシアビレーターONE酢酸エステルを含む廃棄物はどのように処理すべきですか?
アエポキシアビレーターONE酢酸エステルを含む廃棄物は、焼却や専門廃棄処理が一般的です。具体的には、廃棄物は密閉容器に収集し、適切な温度と湿度の下で保存します。...
4-ヒドロキシ但線を取り扱う際の実験室安全事項は何ですか?
取り扱いには化学製品安全管理データシート(SDS)を参照してください。温度10℃以下で保存し、密閉容器に保管してください。漏れ時にはドラフトチャンバーを使用し、...
4-(3-環戊基尿素)フェノールボロネートはどの業界で使用されていますか?
4-(3-環戊基尿素)フェノールボロネートは主に医薬品産業で使用されています。この化合物は抗炎症薬や抗うつ薬の候補物質として研究されています。また、ポリマー産業...
N~1~-[3-氯-5-(三氟甲基)-2-吡啶]-1,2-乙二胺の市場動向や研究トレンドはどうですか?
市場では、安全性と効果性を基にした化学物質の需要が高まっています。研究分野では、環境に優しい代替品の開発が進んでおり、その結果、この化合物の市場需要は減少傾向に...
6-硝基苯并二氢吡喃-4-酮についての法規ガイドラインは何ですか?
6-硝基苯并二氢吡喃-4-酮(CAS番号: 68043-53-8)は、GHS(統一化された化学品の危険性的分類と標識)で急性毒性第4クラスに分類されます。EUで...
6-乙酰基-2(3H)-苯并噻唑酮は安全ですか?
安全性は化合物の使用方法によります。適切な取扱いと防護措置を講じれば、一定の安全性があります。ただし、吸入や皮膚への接触は避けてください。
3-メチル-6-(1-メチルヒドラジニル)ピリジジンはどの業界で使用されていますか?
3-メチル-6-(1-メチルヒドラジニル)ピリジジンは主に医薬品、ポリマー、センサー製造業界で使用されています。特に、医薬品産業では抗がん剤や抗真菌剤の候補物質...
tert-butyl 5-oxo-2,6-diazaspiro[3.4]octane-2-carboxylateの物理化学的性質は何ですか?
tert-butyl 5-オキソ-2,6-ジアザスパイロ[3.4]オクタネ-2-カルボキサongyangはCAS番号1330765-39-3で、分子量は334....
3-塩素メチルフェニル-4,4,5,5-テトラメチル-1,3,2-ジオキソボロラノールは安全ですか?
3-塩素メチルフェニル-4,4,5,5-テトラメチル-1,3,2-ジオキソボロラノールは、毒性が低いと考えられていますが、直接的な皮膚接触や吸入は避けるべきです...
掲載誌
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.














