Pairing of the nucleobases guanine and cytosine in the gas phase studied by IR–UV double-resonance spectroscopy and ab initio calculations
文献情報
Ch. Janzen, P. Imhof, K. Kleinermanns, M. S. de Vries
We present R2PI, IR–UV and UV–UV double resonance measurements of the guanine–cytosine (G–C) dimer formed in a supersonic jet. We show that there is only one isomer of G–C in the investigated wavelength range from 33200 to 34100 cm−1. We assigned the observed G–C isomer to a specific structure, based on comparisons of the IR spectra of the G and C monomers with the G–C dimer in the range of the OH and NH stretching vibrations and ab initio-calculated vibrational frequencies and dimer stabilities. The cluster exhibits an HNH⋯O/NH⋯N/CO⋯HNH bonding similar to the Watson–Crick G–C base pair bonding but with C as the enol tautomer. We did not observe any keto–keto or enol–enol G–C dimers in the investigated wavelength region.
おすすめジャーナル

Nature Medicine

Russian Journal of Applied Chemistry

Organic Process Research & Development

Journal of Natural Medicines

Journal of Peptide Science

Current Opinion in Solid State & Materials Science

Saudi Pharmaceutical Journal

Russian Journal of General Chemistry

Russian Chemical Bulletin

Drug Discovery Today
関連文献
Structure elucidation of bacterial nonribosomal lipopeptides
Sebastian Götze, Pierre Stallforth
DOI: 10.1039/C9OB02539A
β-Selective xylulofuranosylation via a conformationally-restricted glycosyl donor
Bo-Shun Huang, Todd L. Lowary
DOI: 10.1039/D0OB00260G
Free-base porphyrins with localized NH protons. Can substituents alone stabilize the elusive cis tautomer?
Kolle E. Thomas, Christine M. Beavers, Abhik Ghosh
DOI: 10.1039/D0OB00452A
Regioselective catalytic asymmetric N-alkylation of isoxazol-5-ones with para-quinone methides
Suo-Suo Qi, Zhen-Hui Jiang, Ming-Ming Chu, Yi-Feng Wang, Xue-Yang Chen, Wan-Zhen Ju, Dan-Qian Xu
DOI: 10.1039/D0OB00393J
Multiphosphorylated peptides: importance, synthetic strategies, and applications for studying biological mechanisms
Mamidi Samarasimhareddy, Guy Mayer, Mattan Hurevich, Assaf Friedler
DOI: 10.1039/D0OB00499E
Correction: Base-catalyzed C-alkylation of potassium enolates with styrenes via a metal–ene reaction: a mechanistic study
Thierry N. J. Fouquet, Yasuo Norikane
DOI: 10.1039/D0OB90032J
Visible light photoredox catalyzed deprotection of 1,3-oxathiolanes
Mingyang Yang, Zhimin Xing, Bowen Fang, Xingang Xie, Xuegong She
DOI: 10.1039/C9OB02517K
Introducing sequential aza-amino acids units induces repeated β-turns and helical conformations in peptides
Nicolo Tonali, Isabelle Correia, Jacopo Lesma, Guillaume Bernadat, Sandrine Ongeri, Olivier Lequin
DOI: 10.1039/C9OB02654A
Synthesis of trehalose glycolipids
Santanu Jana, Suvarn S. Kulkarni
DOI: 10.1039/D0OB00041H
こちらもおすすめ
アエポキシアビレーターONE酢酸エステルを含む廃棄物はどのように処理すべきですか?
アエポキシアビレーターONE酢酸エステルを含む廃棄物は、焼却や専門廃棄処理が一般的です。具体的には、廃棄物は密閉容器に収集し、適切な温度と湿度の下で保存します。...
4-ヒドロキシ但線を取り扱う際の実験室安全事項は何ですか?
取り扱いには化学製品安全管理データシート(SDS)を参照してください。温度10℃以下で保存し、密閉容器に保管してください。漏れ時にはドラフトチャンバーを使用し、...
4-(3-環戊基尿素)フェノールボロネートはどの業界で使用されていますか?
4-(3-環戊基尿素)フェノールボロネートは主に医薬品産業で使用されています。この化合物は抗炎症薬や抗うつ薬の候補物質として研究されています。また、ポリマー産業...
N~1~-[3-氯-5-(三氟甲基)-2-吡啶]-1,2-乙二胺の市場動向や研究トレンドはどうですか?
市場では、安全性と効果性を基にした化学物質の需要が高まっています。研究分野では、環境に優しい代替品の開発が進んでおり、その結果、この化合物の市場需要は減少傾向に...
6-硝基苯并二氢吡喃-4-酮についての法規ガイドラインは何ですか?
6-硝基苯并二氢吡喃-4-酮(CAS番号: 68043-53-8)は、GHS(統一化された化学品の危険性的分類と標識)で急性毒性第4クラスに分類されます。EUで...
6-乙酰基-2(3H)-苯并噻唑酮は安全ですか?
安全性は化合物の使用方法によります。適切な取扱いと防護措置を講じれば、一定の安全性があります。ただし、吸入や皮膚への接触は避けてください。
3-メチル-6-(1-メチルヒドラジニル)ピリジジンはどの業界で使用されていますか?
3-メチル-6-(1-メチルヒドラジニル)ピリジジンは主に医薬品、ポリマー、センサー製造業界で使用されています。特に、医薬品産業では抗がん剤や抗真菌剤の候補物質...
tert-butyl 5-oxo-2,6-diazaspiro[3.4]octane-2-carboxylateの物理化学的性質は何ですか?
tert-butyl 5-オキソ-2,6-ジアザスパイロ[3.4]オクタネ-2-カルボキサongyangはCAS番号1330765-39-3で、分子量は334....
3-塩素メチルフェニル-4,4,5,5-テトラメチル-1,3,2-ジオキソボロラノールは安全ですか?
3-塩素メチルフェニル-4,4,5,5-テトラメチル-1,3,2-ジオキソボロラノールは、毒性が低いと考えられていますが、直接的な皮膚接触や吸入は避けるべきです...
掲載誌
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.
![(3R)-4-(4-Chlorophenyl)-3-({[(2-methyl-2-propanyl)oxy]carbonyl}amino)butanoic acid structure (3R)-4-(4-Chlorophenyl)-3-({[(2-methyl-2-propanyl)oxy]carbonyl}amino)butanoic acid structure](https://static.chemtradehub.com/structs/218/218608-96-9-f871.webp)



