Phase equilibria of water in cylindrical nanopores

文献情報

出版日 2001-04-05

DOI 10.1039/B100922M

インパクトファクター 3.676

著者

Ivan Brovchenko, Alfons Geiger, Alla Oleinikova

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要旨

Phase equilibria of water in cylindrical nanopores were simulated in the Gibbs ensemble. The decrease of the critical temperature in the confinement compared to the bulk value attains 35% in the pores with radius Rc = 12 Å. The shape of the coexistence curve changes strongly with an increasing water–substrate interaction. This is found to be the result of a crossover from 3D surface to 2D behaviour in the surface layer. At the strongest water–substrate interactions of our study up to 3 coexistence curves are observed due to layering transitions.

掲載誌

Physical Chemistry Chemical Physics

CiteScore: 5.5

自己引用率: 10.3%

年間論文数: 3036

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