Construction of kinetic phase diagrams
文献情報
It is a noted fact that the composition of a mixed solid phase grown at non-equilibrium can deviate from the equilibrium composition due to the very low diffusion rate in the solid phase. We present an analytical model for the determination of the kinetic composition of a binary solid phase that is growing from a solution at a given supersaturation, giving rise to kinetic phase diagrams. The model is derived for growth at rough surfaces but is expected to apply also to growth at non-roughened surfaces. Kinetic phase diagrams for different undercooling and excess energy parameters are presented and discussed. If the interaction parameters, describing the excess free energy, are large the model equations can have two stable solutions, which implies the simultaneous growth of two solid phases with different compositions. This kinetic phase separation depends on the undercooling and the composition dependence of the attachment probabilities.
おすすめジャーナル

Electroanalysis

Acta Metallurgica Sinica-English Letters

Bioorganic & Medicinal Chemistry Letters

Chinese Journal of Chemistry

Cellulose

Herald of the Russian Academy of Sciences

Journal of Asian Natural Products Research

Critical Reviews in Solid State and Materials Sciences

Bioorganic & Medicinal Chemistry

Journal of Chemical Sciences
関連文献
The electronic properties of three popular high spin complexes [TM(acac)3, TM = Cr, Mn, and Fe] revisited: an experimental and theoretical study
S. Carlotto, L. Floreano, A. Cossaro, M. Rancan, M. Sambi
DOI: 10.1039/C7CP04461E
Free-standing reduced graphene oxide/MnO2–reduced graphene oxide–carbon nanotube nanocomposite flexible membrane as an anode for improving lithium-ion batteries
Yong Li, Daixin Ye, Bin Shi, Wen Liu, Rui Guo, Haijuan Pei, Jingying Xie
DOI: 10.1039/C6CP07784F
Circularly polarized laser emission in optically active organic dye solutions
Florencio Moreno, Mizuki Johnson, Gilles Muller, Santiago de la Moya, Inmaculada García-Moreno
DOI: 10.1039/C7CP03303F
A simple bulk modulus model for crystal materials based on the bond valence model
Xiao Liu, Hao Wang, Weimin Wang, Zhengyi Fu
DOI: 10.1039/C7CP03739B
Ferrocene and ferrocenium inclusion compounds with cucurbiturils: a study of metal atom dynamics probed by Mössbauer spectroscopy
Clara I. R. Magalhães, Ana C. Gomes, André D. Lopes, Isabel S. Gonçalves, Martyn Pillinger, Eunyoung Jin, Ikjin Kim, Young Ho Ko, Israel Nowik, Rolfe H. Herber
DOI: 10.1039/C7CP04416J
Deciphering the photosensitization mechanisms of hypericin towards biological membranes
DOI: 10.1039/C7CP03723F
Solvent diffusion in polymer-embedded hollow nanoparticles studied by in situ small angle X-ray scattering
Zhi Hong Chen, Sun Hye Hwang, Xiang-bing Zeng, Jongmin Roh, Jyongsik Jang
DOI: 10.1039/C7CP03741D
Optical properties and magnetic flux-induced electronic band tuning of a T-graphene sheet and nanoribbon
Arka Bandyopadhyay, Atanu Nandy, Arunava Chakrabarti, Debnarayan Jana
DOI: 10.1039/C7CP03983B
Graphitic carbon coupled poly(anthraquinone) for proton shuttle flow-in-a-cell application
Selvam Mathi, Rudra Kumar, Rajaram K. Nagarale, Ashutosh Sharma
DOI: 10.1039/C6CP08419B
Novel benzodithiophene-based polymer acceptors for efficient organic solar cells
Quan-Song Li, Ze-Sheng Li
DOI: 10.1039/C7CP04372D
こちらもおすすめ
「邻羟基阿托伐他汀内酯标准品」に適用される法規ガイドelinesは何ですか?
CAS番号163217-74-1の「邻羟基阿托伐他汀内酯标准品」は、GHS分類では危険物に分類されず、主にREACH規則とFDA/EPAの管理対象となります。R...
メチル(3R)-3-アミノ-2,3-ジヒドロ-1-ベンゾファンラニン-5-カルボイル酸塩塩酸塩の主な用途は何ですか?
メチル(3R)-3-アミノ-2,3-ジヒドロ-1-ベンゾファンラニン-5-カルボイル酸塩塩酸塩は、医薬品や合成化学の研究に広く用いられます。また、特定の薬物の前...
トランス-4-メチルピロリジン-3-オール塩酸塩はどのように合成されますか?
トランス-4-メチルピロリジン-3-オール塩酸塩は、4-メチルピロリジンの塩酸塩化によって合成されます。一般的な合成方法では、4-メチルピロリジンを塩酸に加えて...
硫雜環丁烷-1,1-二氧化物は安全ですか?
硫雜環丁烷-1,1-二氧化物は安全ではありません。毒性は報告されていませんが、高温下で分解し、可燃性があるため、高圧ガスは注意が必要です。密閉した容器で保管し、...
9-ヒドロキシエリプチシネ塩酸塩はどのように合成されますか?
9-ヒドロキシエリプチシネ塩酸塩は、エリプチシネから塩酸を添加することで合成されます。選択性は高いですが、収率は約70%です。
5-塩素-2-(メチルアミノ)フェニル-(2-塩素フェニル)メタン酮の物理化学的性質は何ですか?
5-塩素-2-(メチルアミノ)フェニル-(2-塩素フェニル)メタン酮のCAS番号は5621-86-3です。この化合物は白色の結晶性粉末で、分子量は415.03で...
1-[2-(4-甲氧基-苯氧基)-乙基]-哌嗪はどのように保存すればよいですか?
1-[2-(4-甲氧基-苯氧基)-乙基]-哌嗪は、直射日光を避けて暗所に、室温(15-25℃)で保管し、密閉容器に入れることで安定性を保つことができます。
2-[3-(4-甲氧基フェニル)プロピル]-4,4,5,5-四メチル-1,3,2-ドイボロロールアンの主な用途は何ですか?
2-[3-(4-甲氧基フェニル)プロピル]-4,4,5,5-四メチル-1,3,2-ドイボロロールアンは、医薬品の合成、有機合成化学、および新材料の研究で使用され...
掲載誌
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

![1,1',1'',1'''-[Disulfanediylbis(carbonothioylnitrilo)]tetraethane structure 1,1',1'',1'''-[Disulfanediylbis(carbonothioylnitrilo)]tetraethane structure](https://static.chemtradehub.com/structs/97-/97-77-8-f3e4.webp)


