Transformations of carbohydrate derivatives enabled by photocatalysis and visible light photochemistry

文献情報

出版日 2024-01-02

DOI 10.1039/D3SC05400D

インパクトファクター 9.825

著者

Daniel J. Gorelik, Shrey P. Desai, Sofia Jdanova, Julia A. Turner, Mark S. Taylor

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要旨

This review article highlights the diverse ways in which recent developments in the areas of photocatalysis and visible light photochemistry are impacting synthetic carbohydrate chemistry. The major topics covered are photocatalytic glycosylations, generation of radicals at the anomeric position, transformations involving radical formation at non-anomeric positions, additions to glycals, processes initiated by photocatalytic hydrogen atom transfer from sugars, and functional group interconversions at OH and SH groups. Factors influencing stereo- and site-selectivity in these processes, along with mechanistic aspects, are discussed.

掲載誌

Chemical Science

CiteScore: 14.4

自己引用率: 3.9%

年間論文数: 1413

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Transformations of carbohydrate derivatives enabled by photocatalysis and visible light photochemistry

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