Lewis acid catalysed polymerisation of cyclopentenone

文献情報

出版日 2023-12-02

DOI 10.1039/D3SC05186B

インパクトファクター 9.825

著者

Deepamali Dissanayake, Alysia Draper, Neelofur Jaunnoo, Joris J. Haven, Craig Forsyth, Alasdair I. McKay, Tanja Junkers, Dragoslav Vidović

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要旨

A modest structural change of a β-diketiminate-supported aluminium complex leads to dramatic differences in the reactivity towards cyclopentenone. While the bulkier complex efficiently executes Diels Alder transformations the smaller analogue performs unique polymerisation of this substrate. This observation appears to be unprecedented in the chemistry of Lewis acids and cyclic dienophiles as it represents a unique way to polymerise a functionalised olefin.

掲載誌

Chemical Science

CiteScore: 14.4

自己引用率: 3.9%

年間論文数: 1413

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Lewis acid catalysed polymerisation of cyclopentenone

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