Rapid, iterative syntheses of unsymmetrical di- and triarylboranes from crystalline aryldifluoroboranes

文献情報

出版日 2023-11-17

DOI 10.1039/D3SC05071H

インパクトファクター 9.825

著者

Douglas Turnbull, Marc-André Légaré

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要旨

A one-pot procedure to synthesise aryldifluoroboranes, ArBF2, from bench-stable arylsilanes is presented. These ArBF2 react conveniently with aryllithium reagents to form unsymmetrical ArAr′BF and BArAr′Ar′′ in high yield. Examples of all three classes of borane have been characterised crystallographically, allowing for elucidation of geometric and crystal packing trends in crystalline ArBF2.

掲載誌

Chemical Science

CiteScore: 14.4

自己引用率: 3.9%

年間論文数: 1413

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Rapid, iterative syntheses of unsymmetrical di- and triarylboranes from crystalline aryldifluoroboranes

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