Nascent developments in main group element-catalyzed hydrosilylation and dehydrogenative silylation of alkenes and alkynes

文献情報

出版日 2023-12-13

DOI 10.1039/D3QO01777J

インパクトファクター 5.281

著者

Jiahao Liu, Zhuofeng Ke

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要旨

Hydrosilylation and dehydrogenative silylation of alkenes and alkynes are vital transformations in organic synthesis and have garnered significant attention due to their widespread applications in the preparation of organosilicon materials. Among the catalysts used for hydrosilylation and dehydrogenative silylation reactions, main group elements have emerged as promising alternatives to transition metals due to their abundance, low cost, and minimal toxicity. This review article provides an exhaustive survey of recent advancements in the main group element-catalyzed hydrosilylation and dehydrogenative silylation of alkenes and alkynes. The survey encompasses an in-depth analysis of the diverse catalytic systems developed over the years, highlighting mechanistic insights and their distinct chemo-, regio-, and stereoselectivity. Furthermore, the challenges and limitations researchers face in the field have been addressed, including catalyst design, stability, and substrate compatibility.

掲載誌

Organic Chemistry Frontiers

CiteScore: 7.8

自己引用率: 8.7%

年間論文数: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry