Visible-light-driven C(sp3)–H alkylation of heterobenzylic amines via electron donor–acceptor complexes

文献情報

出版日 2023-11-17

DOI 10.1039/D3QO01765F

インパクトファクター 5.281

著者

Yumei Huo, Beibei Chen, Xiaoyu Ren, Rupeng Qi

原文を見る

要旨

Heterobenzylic amines such as α-alkyl- substituted oxadiazole methylamine skeletons present as essential motifs in pharmaceuticals and pesticides, due to their unique biological activities. Photoredox reactions mediated by electron donor–acceptor (EDA) complexes are relatively environmentally friendly, and have attracted much attention in current organic synthesis research. Herein, we report a C–H alkylation of heterobenzylic amines under visible light irradiation, involving an EDA complex formed upon association of alkyl iodide and organophosphines in catalytic amounts.

掲載誌

Organic Chemistry Frontiers

CiteScore: 7.8

自己引用率: 8.7%

年間論文数: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

Visible-light-driven C(sp3)–H alkylation of heterobenzylic amines via electron donor–acceptor complexes

文献情報

おすすめジャーナル

関連文献

Recent progress in controlling the photoluminescence properties of single-walled carbon nanotubes by oxidation and alkylation

Theoretical analysis of divalent cation effects on aptamer recognition of neurotransmitter targets

Fluorination on cyclopentadithiophene-based hole-transport materials for high-performance perovskite solar cells

Inside front cover

Inside front cover

Cobalt-based tripodal complexes as molecular catalysts for photocatalytic CO2 reduction

Unlocking the reactivity of diazo compounds in red light with the use of photochemical tools

Ratiometric analysis of reversible thia-Michael reactions using nitrile-tagged molecules by Raman microscopy

5- and 10-oxocorroles from β-octaalkylcorroles

Front cover

こちらもおすすめ

3-イチチルビフェニルはどのように合成されますか？

8-溴-5-三氟甲基喹啉はどのように合成されますか？

ジメチル4-(4,4,5,5-テトラメチル-1,3,2-ドioxaborolan-2-基)-2,6-ピリジンジカルボイル酸フェニルアミニドの代替品はありますか？

N-(3,5-ヘキサクロロ-4-ピリドインイル)-8-メチオキシ-5-キノリンカーボン酸の市場動向や研究トレンドはどのようなものでしょうか？

イソステアロイルグリセリルは安全ですか？

1-(二苯甲基)-3,3-二氟-氮杂环丁烷の市場動向や研究トレンドはどうですか？

3-チオフェンスチオールの物理化学的性質は何ですか？

2-Methyl-2-propanyl (2S)-2-(aminomethyl)-1-piperidinecarboxylateは安全ですか？

CAS番号1316822-90-8の化合物は安全ですか？

Tert-butyl 2-(2-羟基乙基)哌嗪-1-羧酸はどのように保存すればよいですか？

掲載誌

Organic Chemistry Frontiers

おすすめ化合物

9,9'-O-Isopropyllidene-isolariciresinol

2-(6-Methylpyridin-3-yl)acetonitrile

3-Bromo-6-chloropicolinamide

N-{3-[Benzyl(methyl)amino]propyl}-9-chloro-5,6,7,8-tetrahydro-2-acridinecarboxamide

Imidazo[1,2-c]pyrimidine

おすすめサプライヤー