Orthogonal polymerization of aziridine with cyclic carbonates for constructing amphiphilic block copolymers

文献情報

出版日 2023-10-31

DOI 10.1039/D3PY01045G

インパクトファクター 5.582

著者

Xiao-Hui Guo, Ge-Ge Gu, Tian-Jun Yue, Wei-Min Ren

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要旨

Herein, we describe a novel strategy for synthesizing amphiphilic block copolymers, comprising acidified polyamine and polycarbonate segments, by the orthogonal polymerization of aziridine and cyclic carbonates. Controlled experiments revealed that the cationic ring-opening polymerization (ROP) of aziridine and the anionic ROP of cyclic carbonates proceeded simultaneously to accomplish chain propagation.

掲載誌

Polymer Chemistry

CiteScore: 8.6

自己引用率: 7.3%

年間論文数: 457

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Orthogonal polymerization of aziridine with cyclic carbonates for constructing amphiphilic block copolymers

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