Ionic plastic crystals and ionic liquids containing quaternary cations with alkenyl substituents: chemical phase transformations by bromine vapor

文献情報

出版日 2024-01-08

DOI 10.1039/D3NJ05633C

インパクトファクター 3.591

著者

Yosuke Nakazono, Ryota Inoue, Ryo Sumitani

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要旨

Ionic Plastic Crystals (IPCs) and Ionic Liquids (ILs) exhibit intriguing physical properties, but methods to chemically control their properties remain largely unexplored. To achieve control over their thermal properties and phase behaviors through chemical reactions, in this study, we synthesized quaternary salts comprising ammonium cations with vinyl or allyl substituents and fluorinated anions. Most of them were IPCs or ILs, which readily underwent quantitative bromine addition reactions upon exposure to bromine vapor. The reactions facilitated simple, efficient chemical phase transformations between IPCs, ILs, and ordinary ionic crystals.

掲載誌

New Journal of Chemistry

CiteScore: 5.3

自己引用率: 3.7%

年間論文数: 2153

NJC (New Journal of Chemistry) is a broad-based primary journal encompassing all branches of chemistry and its sub-disciplines. It contains full research articles, communications, perspectives and focus articles. This well-established journal, owned by the Centre National de la Recherche Scientifique (CNRS) of France, has been co-published with the Royal Society of Chemistry since January 1998. NJC is the forum for the publication of high-quality, original and significant work that opens new directions in chemistry or other scientific disciplines. In addition to having a significant chemical component, work published in NJC must demonstrate that it will have an impact on areas of research other than that of the reported work.

Ionic plastic crystals and ionic liquids containing quaternary cations with alkenyl substituents: chemical phase transformations by bromine vapor

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