Localized surface plasmon resonance assisted photoredox catalysis using newly fabricated copper-nanorods: a decarboxylative approach towards carbon–hydrogen bond formation under visible light

文献情報

出版日 2023-11-28

DOI 10.1039/D3NJ04195F

インパクトファクター 3.591

著者

Saikat Khamarui, Sirshendu Ghosh

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要旨

The plasmonic behaviour of synthesized copper nanorods (Cu-NRs) plays an important role in redox processes as well as in coupling. A benign decarboxylative approach is developed to produce alkane analogues from corresponding alkyl carboxylic acids using these Cu-NRs via localised surface plasmon resonance (LSPR) assisted catalysis under visible light. A broad substrate scope and functional group tolerance are observed without any external oxidant or proton source. A plausible mechanism has also been proposed for this recyclable nano-catalyst based on some control experiments.

掲載誌

New Journal of Chemistry

CiteScore: 5.3

自己引用率: 3.7%

年間論文数: 2153

NJC (New Journal of Chemistry) is a broad-based primary journal encompassing all branches of chemistry and its sub-disciplines. It contains full research articles, communications, perspectives and focus articles. This well-established journal, owned by the Centre National de la Recherche Scientifique (CNRS) of France, has been co-published with the Royal Society of Chemistry since January 1998. NJC is the forum for the publication of high-quality, original and significant work that opens new directions in chemistry or other scientific disciplines. In addition to having a significant chemical component, work published in NJC must demonstrate that it will have an impact on areas of research other than that of the reported work.

Localized surface plasmon resonance assisted photoredox catalysis using newly fabricated copper-nanorods: a decarboxylative approach towards carbon–hydrogen bond formation under visible light

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