Tailoring hydroxyl groups of organic phenazine anodes for high-performance and stable alkaline batteries

文献情報

出版日 2023-11-21

DOI 10.1039/D3EE01212C

インパクトファクター 38.532

著者

Zhuoxi Wu, Jiaxiong Zhu, Chuan Li, Xiaoqi Wang, Xu Jin, Shengchi Bai

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要旨

Alkaline-based aqueous batteries have attracted intensive research interests due to their high voltage, low cost, and high safety. However, metal anodes in alkaline electrolytes usually possess poor stability and severe side reactions. Organics are potential alternatives to address these problems, but they are typically not negative enough as anodes. Herein, a group of organic phenazine derivatives including phenazine (PZ), 2-hydroxyphenazine (PZ-OH), and 1,2-dihydroxyphenazine (PZ-2OH) are developed as anode materials for alkaline-based batteries. It is revealed that introducing hydroxyl groups can lower the redox potential by 0.4 V, and fast ion transport channels formed by intramolecular hydrogen bonds can remarkably improve redox kinetics. The optimized PZ-2OH‖Ni (OH)2 batteries deliver a high capacity of 208 mA h g−1anode, a high energy density of 247 W h kg−1anode, and ultra-stable cyclability up to 9000 cycles with a low-capacity decay rate (approximately 0.075‰ capacity decay rate per cycle). Meanwhile, we also demonstrate an alkaline PZ-2OH‖air cell, further proving the applicability of PZ-2OH under alkaline conditions. This work not only explores the effect of hydroxyl substituents on the electrochemical potential and reaction kinetics but also opens up the door to stable anodes for alkaline-based batteries.

掲載誌

Energy & Environmental Science

CiteScore: 32.34

自己引用率: 3.4%

年間論文数: 481

Energy & Environmental Science is an international journal dedicated to publishing exceptionally important and high quality, agenda-setting research tackling the key global and societal challenges of ensuring the provision of energy and protecting our environment for the future. The scope is intentionally broad and the journal recognises the complexity of issues and challenges relating to energy conversion and storage, alternative fuel technologies and environmental science. For work to be published it must be linked to the energy-environment nexus and be of significant general interest to our community-spanning readership. All scales of studies and analysis, from impactful fundamental advances, to interdisciplinary research across the (bio)chemical, (bio/geo)physical sciences and chemical engineering disciplines are welcomed. Topics include, but are not limited to, the following: Solar energy conversion and photovoltaics Solar fuels and artificial photosynthesis Fuel cells Hydrogen storage and (bio) hydrogen production Materials for energy systems Capture, storage and fate of CO2, including chemicals and fuels from CO2 Catalysis for a variety of feedstocks (for example, oil, gas, coal, biomass and synthesis gas) Biofuels and biorefineries Materials in extreme environments Environmental impacts of energy technologies Global atmospheric chemistry and climate change as related to energy systems Water-energy nexus Energy systems and networks Globally applicable principles of energy policy and techno-economics

Tailoring hydroxyl groups of organic phenazine anodes for high-performance and stable alkaline batteries

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