Impact of exposed crystal facets on oxygen reduction reaction activity in zeolitic imidazole frameworks

文献情報

出版日 2023-08-08

DOI 10.1039/D3DT02172F

インパクトファクター 4.39

著者

Sorawich Pimu, Nuttapon Yodsin, Sirawee Maneewan, Jaruwan Kanthachan, Supawadee Namuangruk, Kanokwan Kongpatpanich

原文を見る

要旨

ZIF-67 is a representative type of metal–organic framework (MOF) developed for the oxygen reduction reaction (ORR) owing to its robust structure in alkaline electrolytes and the presence of the redox-active Co2+ species in the structure. In this work, the improvement of the ORR electrolytic performance of ZIF-67 in its pure phase by optimization of its crystal morphology and crystal facets has been presented. ZIF-67 nanocubes exhibit higher ORR activity than their bulk crystals. The enriched (100) facet in the nanocube crystals provides a higher number of exposed Co2+ sites resulting in improved ORR performances. Moreover, DFT study suggests a distinguished mechanism in the (100) facet highlighting the importance of crystal facets in electrochemical performances.

掲載誌

Dalton Transactions

CiteScore: 6.6

自己引用率: 11.4%

年間論文数: 1868

Dalton Transactions is a journal for all areas of inorganic chemistry, which encompasses the organometallic, bioinorganic and materials chemistry of the elements, with applications including synthesis, catalysis, energy conversion/storage, electrical devices and medicine. Dalton Transactions welcomes high-quality, original submissions in all of these areas and more, where the advancement of knowledge in inorganic chemistry is significant. Specific guidance for some areas of our scope is given below.

Impact of exposed crystal facets on oxygen reduction reaction activity in zeolitic imidazole frameworks

文献情報

おすすめジャーナル

関連文献

Morphology – composition correlations in carbon nanotubes synthesised with nitrogen and phosphorus containing precursors

An experimental and theoretical study of the gas phase kinetics of atomic chlorine reactions with CH3NH2, (CH3)2NH, and (CH3)3N

“Tschitschibabin type biradicals”: benzenoid or quinoid?

Bio-inspired fabrication of hierarchical Ni–Fe–P coated skin collagen fibers for high-performance microwave absorption

Stability and spinodal decomposition of the solid-solution phase in the ruthenium–cerium–oxide electro-catalyst

Exploring the complexity of quantum control optimization trajectories

Pentaglyme–K salt binary mixtures: phase behavior, solvate structures, and physicochemical properties

Illuminating surface atoms in nanoclusters by differential X-ray absorption spectroscopy

Contents list

Are thermodynamic cycles necessary for continuum solvent calculation of pKas and reduction potentials?

こちらもおすすめ

1-{3-[5-(エチルカルボンイル)-2,4-ジメチル-1H-ピロロール-3-基]プロパニル}ピペリジン-4-カルボン酸について、適用される法規ガイドラインは何ですか？

2,2-二氟-1,3-ベンゾジオキサン-5-カルボキシlic酸とは何ですか？

8-氯-4-色原酮の代替品はありますか？

エチル6,6-ジメチル-4,5,6,7-テトラヒドロ-1H-インドアゼー-3-カルボキシレートとは何ですか？

4-叔丁基-6-氯-嘧啶に適用される法規ガイドラインは何ですか？

維库溴铵杂质Bはどのように合成されますか？

2-(4-氟苄基)-吡咯烷の物理化学的性質は何ですか？

3-喹啉甲醛（2-チロール-8-エチル）は安全ですか？

エチル3-(ヒドロキシメチル)-1H-ピロール-2-カルボキシレートはどのように保存すればよいですか？

哌拉西林杂质Dは安全ですか？

掲載誌

Dalton Transactions

おすすめ化合物

Zinc bis(O,O-diheptyl phosphorodithioate)

Diphenyl hydrogen phosphate

1,3,5-Trichloro-1,3,5-triazinane-2,4,6-trione

Bis[(1,2,3,4,5-eta)-1-(diphenylphosphino)cyclopentadienyl]iron

Methyl 4-chloro-2-pyridinecarboxylate

おすすめサプライヤー