Tuning interfaces between Cu and oxide via atomic layer deposition method for CO2 hydrogenation to methanol

文献情報

出版日 2023-12-02

DOI 10.1039/D3CY01221B

インパクトファクター 6.119

著者

Kun Jiang, Huibo Zhao, Yang Chen, Baozhen Li, Zhang Zhang, Fenghai Cao, Lizhi Wu, Yu Tang, Li Tan

原文を見る

要旨

Tailoring the metal–oxide interface by atomic layer deposition (ALD) is a promising strategy to modulate active sites for methanol synthesis from CO2 hydrogenation. Herein, specific Cu/ZnOx/CeO2 interfaces are constructed by controlling the deposition sequence and amount of ZnO in Cu–Zn–Ce oxide catalysts via the ALD method. In-depth characterizations demonstrate that Cu+–Zn0–Ce4+ structure is the active site for methanol synthesis from CO2 hydrogenation. This strategy provides a viable way to tune the metal–oxide interface to develop catalysts and favors precise understanding of the catalytic–structure activity relationship of the Cu species in the process of CO2 conversion to methanol.

掲載誌

Catalysis Science & Technology

CiteScore: 5.91

自己引用率: 4.5%

年間論文数: 600

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