Stannaborates: tuning the ion conductivity of dodecaborate salts with tin substitution
文献情報
Thomas A. Hales, Terry D. Humphries, Anita M. D’Angelo, Craig E. Buckley, Mark Paskevicius
Metal substituted dodecaborate anions can be coupled with alkali metal cations to have great potential as solid-state ion conductors for battery applications. A tin atom can replace a B–H unit within an unsubstituted dodecaborate cage to produce a stable, polar divalent anion. The chemical and structural change in forming a stannaborate results in a modified crystal structure of respective group 1 metal salts, and as a result, improves the material's ion conductivity. Li2B11H11Sn shows high ion conductivity of ∼8 mS cm−1 at 130 °C, similar to the state-of-the-art LiCB11H12 at these temperatures, however, obtaining high ion conductivity at room temperature is not possible with pristine alkali metal stannaborates.
おすすめジャーナル

Heteroatom Chemistry

NDT & E International

Main Group Chemistry

Journal of Asian Natural Products Research

Journal of the Indian Institute of Science

Herald of the Russian Academy of Sciences

Atomization and Sprays

Biocatalysis and Biotransformation

Topics in Catalysis

Acta Metallurgica Sinica-English Letters
関連文献
Rapid and low-cost amplicon visualization for nucleic acid amplification tests using magnetic microbeads
Michihiko Nakano, Masafumi Inaba, Junya Suehiro
DOI: 10.1039/D0AN02349C
Carbon dots as naked eye sensors
Hafiz Muhammad Junaid, Amber Rehana Solangi, Madeeha Batool
DOI: 10.1039/D0AN02399J
MoS2/Pt nanocomposite-functionalized microneedle for real-time monitoring of hydrogen peroxide release from living cells
Jin-Xiu Zhou, Fan Yang
DOI: 10.1039/C7AN01446E
Low-cost laser-cut patterned chips for acoustic concentration of micro- to nanoparticles and cells by operating over a wide frequency range
Jingui Qian, Wei Huang, Renhua Yang, Raymond H. W. Lam
DOI: 10.1039/D1AN00197C
Covalent-coordination tandem functionalization of a metal–organic framework (UiO-66) as a hybrid probe for luminescence detection of trans,trans-muconic acid as a biomarker of benzene and Fe3+
Jie Min, Xiang-Long Qu
DOI: 10.1039/D0AN02467H
Synthesis of low polydispersity, controlled-structure sugar methacrylate polymers under mild conditions without protecting group chemistry
Ravin Narain, Steven P. Armes
DOI: 10.1039/B208654A
Convenient hyaluronidase biosensors based on the target-trigger enhancing of the permeability of a membrane using an electronic balance as a readout
Qing Cai, Zhixin Li, Liangzhen Xu, Bin Qiu, Cheng Li, Zhenyu Lin
DOI: 10.1039/D1AN00257K
Comparing the abundance of HClO in cancer/normal cells and visualizing in vivo using a mitochondria-targeted ultra-fast fluorescent probe
Qian Pang, Tao Li, Caixia Yin, Kaiqing Ma, Fangjun Huo
DOI: 10.1039/D1AN00375E
Vinyl-λ3-iodanes act as efficient sulfur atom acceptors: vinylic SN2-based strategy for conversion of tertiary thioamides to amides
Masahito Ochiai, Shinji Yamamoto
DOI: 10.1039/B209097J
こちらもおすすめ
6-苄基-6,7-二氢-5H-吡咯并3,4-b吡啶とは何ですか?
6-苄基-6,7-二氢-5H-吡咯并3,4-b吡啶は、CAS番号109966-30-5の化合物です。これは、6-ベンジル基を持つ6,7-二氢-5H-吡咯並みの化...
半硫酸奎宁单水水合物はどのように保存すればよいですか?
半硫酸奎宁单水水合物は、乾燥した涼しい場所に保管し、直射日光や湿気を避ける必要があります。保存温度は常温(15〜25℃)が適切で、湿度は40%以下を維持すること...
D-核糖-5-リン酸二ナトリウムとは何ですか?
D-核糖-5-リン酸二ナトリウムは、CAS番号18265-46-8を有する化合物で、D-核糖の5位付加部位にリン酸基が結合した化合物です。この化合物は、水溶性で...
3-乙酰基-4-羟基喹啉-2(1H)-酮はどのように合成されますか?
3-乙酰基-4-羟基喹啉-2(1H)-酮は、ハイドロキノンと酢酸アセトイルアミドのアミド化反応により合成されます。この反応は塩基触媒を用いて行われ、選択性は良好...
5-溴-4-甲基-1H-吲唑とは何ですか?
5-溴-4-甲基-1H-吲唑は、CAS番号1082041-34-6の化学物質で、化学式はC10H9BrNです。この化合物は淡黄色の結晶性粉末で、吸湿性があります...
3-(4メトキシフェニル)オキテナン-3カーボイル酸の代替品はありますか?
3-(4メトキシフェニル)オキテナン-3カーボイル酸の代替品は、その用途により異なりますが、例えば4-(メトキシフェニル)オキテナン-3カーボイル酸や、他のオキ...
3-イリドオキシピロロ[2,3-b]ピリジン-5-カルボキシlic酸は安全ですか?
3-イリドオキシピロロ[2,3-b]ピリジン-5-カルボキシlic酸は危険な化合物ではありませんが、適切な手袋や保護眼鏡の使用を推奨します。誤って摂取または接触...
3-氟-4- iodobenolを取り扱う際の実験室安全事項は何ですか?
3-氟-4- iodobenolは可燃性を有し、強力な反応性を持つため、取り扱いには注意が必要です。PPE(個人保護具)の着用、ドラフトチャンバーの使用、漏洩時...
掲載誌
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.




