[RbSr3X][(BS3)2] (X = Cl, Br): two salt-inclusion thioborates with large birefringence and structure transformation from centrosymmetric to asymmetric

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出版日 2023-11-18

DOI 10.1039/D3CC05205B

インパクトファクター 6.222

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要旨

[RbSr3X][(BS3)2] (X = Cl, Br), two salt-inclusion chalcogenides with planar [BS3] as anionic units, were obtained. Structure analysis indicates that the size effect of halogens may adjust the arrangement between the [BS3] units and further lead to the CS-to-NCS structure transformation. Experimental characterizations reveal that they have wide bandgaps (3.64–3.70 eV), large birefringence (0.136–0.144) and high LIDT (12–14 × AgGaS2). This work indicates that the thioborate family is a rich source to explore structure chemistry and promising infrared functional materials.

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Chemical Communications

CiteScore: 8.6

自己引用率: 4.7%

年間論文数: 2458

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

[RbSr3X][(BS3)2] (X = Cl, Br): two salt-inclusion thioborates with large birefringence and structure transformation from centrosymmetric to asymmetric

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