Visible-light driven electron–donor–acceptor (EDA) complex-initiated synthesis of thio-functionalized pyridines

文献情報

出版日 2023-05-12

DOI 10.1039/D3CC01678A

インパクトファクター 6.222

著者

Hirendra Nath Dhara, Amitava Rakshit, Dinabandhu Barik, Koustuv Ghosh, Bhisma K. Patel

原文を見る

要旨

A visible/solar-light-induced electron–donor–acceptor (EDA)-aggregated/mediated radical cyclization between (E)-2-(1,3-diarylallylidene)malononitriles and thiophenols leads to poly-functionalized pyridines. The two reacting partners form an EDA complex that absorbs light and triggers the single-electron transfer (SET) to generate a thiol radical, which undergoes addition/cyclization with dicyanodiene through the formation of C–S and C–N bonds.

掲載誌

Chemical Communications

CiteScore: 8.6

自己引用率: 4.7%

年間論文数: 2458

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