Oxidation of HOSO˙ by O2 (3Σg−): a key reaction deciding the fate of HOSO˙ in the atmosphere
文献情報
Philips Kumar Rai, Saptarshi Sarkar, Biman Bandyopadhyay, Pradeep Kumar
In the present work, we have studied the oxidation of HOSO˙ by O2 (3Σg−) employing quantum chemical and kinetic calculations. The present work reveals that HOSO˙ + O2 (3Σg−) is a barrierless reaction which proceeds through a stable hydrogen-bonded complex. The estimated atmospheric lifetime of HOSO˙ in the presence of O2 (3Σg−) is found to be several orders of magnitude less compared to the other oxidation paths of HOSO˙, suggesting that the oxidation of HOSO˙ by O2 (3Σg−) might be the most dominant oxidation path of HOSO˙ in the atmosphere.
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