Sulfur stereogenic centers in transition-metal-catalyzed asymmetric C–H functionalization: generation and utilization

文献情報

出版日 2021-07-07

DOI 10.1039/D1SC02614C

インパクトファクター 9.825

著者

Wentan Liu, Jie Ke, Chuan He

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要旨

Transition-metal-catalyzed enantioselective C–H functionalization has emerged as a powerful tool for the synthesis of enantioenriched compounds in chemical and pharmaceutical industries. Sulfur-based functionalities are ubiquitous in many of the biologically active compounds, medicinal agents, functional materials, chiral auxiliaries and ligands. This perspective highlights recent advances in sulfur functional group enabled transition-metal-catalyzed enantioselective C–H functionalization for the construction of sulfur stereogenic centers, as well as the utilization of chiral sulfoxides to realize stereoselective C–H functionalization.

掲載誌

Chemical Science

CiteScore: 14.4

自己引用率: 3.9%

年間論文数: 1413

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Sulfur stereogenic centers in transition-metal-catalyzed asymmetric C–H functionalization: generation and utilization

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