One-pot three-step mechanically assisted synthesis and catalytic performance of tripodal metallic complexes

文献情報

出版日 2021-07-20

DOI 10.1039/D1RE00194A

インパクトファクター 4.239

著者

Raquel Viveiros, Teresa Casimiro

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要旨

Mechanosynthesis is an emergent green technology that can be applied under solventless or vestigial solvent conditions. Major advantages lie in waste reduction and lower energy consumption, without compromising or enhancing reaction conversion. In this work, we reported for the first time a one-pot three-step, ligand to catalysis, mechanically assisted synthesis. Tripodal nitrogen-based ligands were complexed with different metals, and these new metallic complexes, produced in high yield, were further investigated in the mechanically assisted oxidation of (R)-limonene. Using m-chloroperbenzoic acid as the oxidant and the iron complex, under solventless conditions at room temperature, (R)-limonene was selectively oxidized (77.5%) to dihydrocarvone in quantitative yield for short reaction time.

掲載誌

Reaction Chemistry & Engineering

CiteScore: 0

自己引用率: 8.8%

年間論文数: 284

Reaction Chemistry & Engineering is an interdisciplinary journal reporting cutting-edge research focused on enhancing the understanding and efficiency of reactions. Reaction engineering leverages the interface where fundamental molecular chemistry meets chemical engineering and technology. Challenges in chemistry can be overcome by the application of new technologies, while engineers may find improved solutions for process development from the latest developments in reaction chemistry. Reaction Chemistry & Engineering is a unique forum for researchers whose interests span the broad areas of chemical engineering and chemical sciences to come together in solving problems of importance to wider society. All papers should be written to be approachable by readers across the engineering and chemical sciences. Papers that consider multiple scales, from the laboratory up to and including plant scale, are particularly encouraged.

One-pot three-step mechanically assisted synthesis and catalytic performance of tripodal metallic complexes

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