Synthesis of 2-trifluoromethylquinolines through rhodium-catalysed redox-neutral [3 + 3] annulation between anilines and CF3-ynones using traceless directing groups

文献情報

出版日 2021-11-29

DOI 10.1039/D1QO01478A

インパクトファクター 5.281

著者

Haichao Huang, Hailong Wang, Chao Gong, Zhenjing Zhuang, Wenmin Feng, Si-Hai Wu, Lianhui Wang

原文を見る

要旨

Rhodium-catalysed regioselective redox-neutral [3 + 3]-cycloaddition of anilines with CF3-ynones was achieved via a traceless directing group strategy. A variety of substituted 2-trifluromethylquinoline compounds were obtained in good to excellent yields, which exhibited favorable blue emission properties.

掲載誌

Organic Chemistry Frontiers

CiteScore: 7.8

自己引用率: 8.7%

年間論文数: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

Synthesis of 2-trifluoromethylquinolines through rhodium-catalysed redox-neutral [3 + 3] annulation between anilines and CF3-ynones using traceless directing groups

文献情報

おすすめジャーナル

関連文献

Improved 3D DOSY-TOCSY experiment for mixture analysis

Contents and Chemical Technology

Remote substituent effects on the photooxygenation of 9,10-diarylanthracenes: strong evidence for polar intermediates

Chemical modifications of AFM tips for the study of molecular recognition events

Unconventional thermodynamically stable cis isomer and trans to cis thermal isomerization in reversibly photoresponsive [0.0](3,3′)-azobenzenophane

Front cover

High-level QM/MM modelling predicts an arginine as the acid in the condensation reaction catalysed by citrate synthase

Template-controlled topochemical photodimerization based on “organometallic macrocycles” through single-crystal to single-crystal transformation

Benzo[1,2-b:4,5-b′]bis[b]benzothiophene as solution processible organic semiconductor for field-effect transistors

An unusual dianion equivalent from acylsilanes for the synthesis of substituted β-keto esters

こちらもおすすめ

3-イチチルビフェニルはどのように合成されますか？

8-溴-5-三氟甲基喹啉はどのように合成されますか？

ジメチル4-(4,4,5,5-テトラメチル-1,3,2-ドioxaborolan-2-基)-2,6-ピリジンジカルボイル酸フェニルアミニドの代替品はありますか？

N-(3,5-ヘキサクロロ-4-ピリドインイル)-8-メチオキシ-5-キノリンカーボン酸の市場動向や研究トレンドはどのようなものでしょうか？

イソステアロイルグリセリルは安全ですか？

1-(二苯甲基)-3,3-二氟-氮杂环丁烷の市場動向や研究トレンドはどうですか？

3-チオフェンスチオールの物理化学的性質は何ですか？

2-Methyl-2-propanyl (2S)-2-(aminomethyl)-1-piperidinecarboxylateは安全ですか？

CAS番号1316822-90-8の化合物は安全ですか？

Tert-butyl 2-(2-羟基乙基)哌嗪-1-羧酸はどのように保存すればよいですか？

掲載誌

Organic Chemistry Frontiers

おすすめ化合物

(3alpha,5beta,6alpha,7alpha)-6-Ethylcholane-3,7,24-triol

N-Methyl-3-(1-naphthyloxy)-3-(2-thienyl)-1-propanamine hydrochloride (1:1)

8-Bromo-7-fluoro-2-methoxyquinoline

2-Methyl-2-propanyl 2-carbamimidoyl-1-piperidinecarboxylate

2-Cyano-N-cyclopentylacetamide

おすすめサプライヤー