Synthesis of 2-trifluoromethylquinolines through rhodium-catalysed redox-neutral [3 + 3] annulation between anilines and CF3-ynones using traceless directing groups

文献情報

出版日 2021-11-29

DOI 10.1039/D1QO01478A

インパクトファクター 5.281

著者

Haichao Huang, Hailong Wang, Chao Gong, Zhenjing Zhuang, Wenmin Feng, Si-Hai Wu, Lianhui Wang

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要旨

Rhodium-catalysed regioselective redox-neutral [3 + 3]-cycloaddition of anilines with CF3-ynones was achieved via a traceless directing group strategy. A variety of substituted 2-trifluromethylquinoline compounds were obtained in good to excellent yields, which exhibited favorable blue emission properties.

掲載誌

Organic Chemistry Frontiers

CiteScore: 7.8

自己引用率: 8.7%

年間論文数: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

Synthesis of 2-trifluoromethylquinolines through rhodium-catalysed redox-neutral [3 + 3] annulation between anilines and CF3-ynones using traceless directing groups

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