Palladium catalyzed desulfurative coupling of allyl sulfides with organoboronic acids

文献情報

出版日 2021-09-29

DOI 10.1039/D1QO01106E

インパクトファクター 5.281

著者

Yan-Yan Guan, Xiao-Xue Wu, Yu-Fang Liu, Jian-Bin Chao, Zhen-Kang Wen

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要旨

A palladium catalyzed desulfurative coupling of allylthioethers with organoboronic acids under mild reaction conditions is described. The reaction exhibits high chemoselectivity and good functional group tolerance, allowing the synthesis of a wide range of α-branched enones. In addition, this approach enables a new retrosynthetic disconnection to multi-functionalised allylic molecules via selective cleavage of the C–S bond, thus providing a complementary allylation protocol to Tsuji–Trost reactions.

掲載誌

Organic Chemistry Frontiers

CiteScore: 7.8

自己引用率: 8.7%

年間論文数: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

Palladium catalyzed desulfurative coupling of allyl sulfides with organoboronic acids

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